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Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( ${\mathrm{logCO}}_{\mathrm{MMR}}=-{1.1}_{-0.6}^{+0.4}$), H₂O ( ${\mathrm{logH}}_2{\mathrm{O}}_{\mathrm{MMR}}=-{4.1}_{-0.9}^{+0.7}$), and OH ( ${\mathrm{logOH}}_{\mathrm{MMR}}=-{2.1}_{-1.1}^{+0.5}$), suggesting near-complete dayside photodissociation of H₂O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of ${0.8}_{-0.2}^{+0.1}$, consistent with the accretion of high-metallicity gas near the CO₂snow line and post-disk migration or with accretion between the soot and H₂O snow lines. We also find tentative evidence for¹²CO/¹³CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 

Abstract Using the Keck Planet Imager and Characterizer, we obtained high-resolution (R∼ 35,000)K-band spectra of the four planets orbiting HR 8799. We clearly detected H₂O and CO in the atmospheres of HR 8799 c, d, and e, and tentatively detected a combination of CO and H₂O in b. These are the most challenging directly imaged exoplanets that have been observed at high spectral resolution to date when considering both their angular separations and flux ratios. We developed a forward-modeling framework that allows us to jointly fit the spectra of the planets and the diffracted starlight simultaneously in a likelihood-based approach and obtained posterior probabilities on their effective temperatures, surface gravities, radial velocities, and spins. We measured $v\sin \left(i\right)$values of ${10.1}_{-2.7}^{+2.8}\mathrm{km}{\mathrm{s}}^{-1}$for HR 8799 d and ${15.0}_{-2.6}^{+2.3}\mathrm{km}{\mathrm{s}}^{-1}$for HR 8799 e, and placed an upper limit of <14 km s⁻¹of HR 8799 c. Under two different assumptions of their obliquities, we found tentative evidence that rotation velocity is anticorrelated with companion mass, which could indicate that magnetic braking with a circumplanetary disk at early times is less efficient at spinning down lower-mass planets.